Product ID:SOLVENT 111 DF
MSDS Date:02/01/1990
FSC:6810
NIIN:00-664-0387
MSDS Number: BKBDG

VULCAN MATERIALS CO

BIRMINGHAM, AL 35253-0689
US

Emergency Phone: 316-524-5751

Info Phone: 205-877-3459 / 415-821-5338

Cage: 1B637

VULCAN MATERIALS CO

530390 BIRMINGHAM, AL 35253 US

Telephone: 316-524-5751

Cage: 1B637

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: > 95%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

GLYCOL METHYLENE ETHER

CAS: 646-06-0

RTECS: JH6760000

Fraction By Weight: < 3%

SEC-BUTYL ALCOHOL (SARA III)

CAS: 78-92-2

RTECS: EO1750000

Fraction By Weight: < 2%

OSHA PEL 150 PPM

ACGIH TLV: 100 PPM; 9293

1,2-BUTYLENE OXIDE (SARA III)

CAS: 106-88-7

RTECS: EK3675000

Fraction By Weight: < 5%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:BLOOD PRESS DEPRESS,CARDIAC
SENSITIZATION/VENTRICULAR ARRHYTHMIA CAN RESULT FROM THE EXPOS TO
NEAR ANESTHETIC LEVELS.SECONDARY BUTANOL AS PURE SUBSTANCE HAS
CAUSED SEVERE CORNEAL INJURY IN RABBITS/IS ABSORBED READILY FROM
THE GASTROINTESTINAL TRACT & CAN CAUSE CENTRAL NERVE SYSTEM
DEPRESS.LIVER TOXIC EFFECTS IN ANIMALS
Explanation of Carcinogenicity:1,1,1TRICHLOROETHANE,GLYCOL METHYLENE
ETHER,SECONDARY BUTYLENE OXIDE ARE NOT LISTED ON OSHA,IARC,OR NTP
CARCINOGEN LIST
Effects of Overexposure:INHALED:DIZZINESS,DROWSINESS,& THROAT IRRIT AT
LEVELS ABOVE 1,000PPM.UNCONSCIOUSNESS & DEATH POSSIBLE ABOVE
10,000PPM.SKIN:IRRIT,DEFATTING OF SKIN & DERMATITIS.ABSORPTION IS
POSS IF CONTACT IS PROLONG ED.EYES:IRRIT W/SLIGHT TEMP CORNEAL
INJURY.INGESTION:CAN BE ASPIRATED INTO LUNGS CAUSING CHEM
PNEUMONIA/SYSTEMIC EFFECTS
Medical Cond Aggravated by Exposure:ACUTE AND CHRONIC LIVER DISEASE AND
RHYTHM DISORDERS OF THE HEART.

First Aid:INHALED:REMOVE TO FRESH AIR.IF BREATHING STOPPED,GIVE ART
RSPRTN.CALL DOCTOR.SKIN:REMOVE CONTAMIN CLOTHING/SHOES.WASH AREA
W/SOAP/WATER.WASH CONTAMIN CLOTHES BEFORE REUSE.EYES:FLUSH W/WATER
FOR 15 MIN UTES.IF IRRIT PERSISTS,CALL DOCTOR.INGESTED:DO NOT
INDUCE VOMIT.CONTACT DOCTOR/EMERG MED FACILITY IMMED.NOTE TO
PHYSICIAN:ADRENALIN SHOULD NEVER BE GIVEN TO PERSONS OVEREXPOS TO
1,1,1,TRICHLOROETHANE.

Flash Point:NONE
Lower Limits:7.5
Upper Limits:15
Extinguishing Media:WATER, FOAM, DRY CHEMICAL, CARBON DIOXIDE (CO2)
Unusual Fire/Explosion Hazard:CONCENTRATED VAPORS CAN BE IGNITED BY
HIGH INTENSITY IGNIT SOURCE.FIREFIGHTERS SHOULD WEAR SELF
CONTAINED,POSITIVE-PRESS BREATHING APPARATUS/AVOID SKIN CONTACT.

Spill Release Procedures:EVACUATE AREA.VENTILATE & AVOID BREATHING
VAPORS.DIKE AREA TO CONTAIN SPILL.CLEAN UP AREA(WEAR PROT EQUIP)BY
MOPPING OR W/ABSORBENT MAT'L & PLACE IN CLOSED CONTAINERS FOR
DISPOSAL.AVOID CONTAMINATION OF GROUND & SURFACE WATER.DO NOT
FLUSH TO SEWER.*

Handling and Storage Precautions:STORE LABELED/SEALED CONTAINERS IN
COOL,DRY,WELL-VENTED AREA.PREVENT WATER/MOIST AIR FROM ENTERING
STORAGE TANK/CONTAINERS.DO NOT WELD/CUT ON EMPTY DR
Other Precautions:DO NOT USE ALUMINUM EQUIP FOR STORAGE/TRANSFER.VAPORS
ARE HEAVIER THAN AIR/COLLECT IN LOW AREAS.DO NOT ENTER CONFINED
SPACES AS TANKS/PIT W/OUT FOLLOWING PROPER PROCED.CONTACT
W/ALUMINUM PARTS IN A FL UID SYSTEM MAY CAUSE VIOLENT REACTION.**

Respiratory Protection:WHERE VAPOR CONCEN EXCEED/LIKELY TO EXCEED
350PPM,A NIOSH/MSHA APPROVED ORGANIC VAPOR TYPE RSPRTR IS
ACCEPTABLE.A NIOSH/MSHA APPROVED SCBA OR AIR LINE RSPRTR W/FULL
FACE PIECE IS REQUIRED FOR VAPOR CO NCEN ABOVE 1,000PPM/SPILLS OR
EMERGENCY.
Ventilation:DO NOT USE IN CLOSED/CONFINED SPACE. OPEN DOORS AND/OR
WINDOWS. USE VENTILATION TO MAINTAIN EXPOSURE LEVELS BELOW 350PPM
Protective Gloves:VITON,POLYVINYL ALCOHOL OR EQUIVALENT.
Eye Protection:SAFETY GLASSES.CHEM GOG.NO CONTACT LENS.
Other Protective Equipment:SOLVENT RESISTANT BOOTS,APRON,HEADGEAR &/OR
FACESHIELD SHOULD BE WORN WHERE SPLASHING IS POSSIBLE.SAFETY
SHOWER/EYEWASH.
Work Hygienic Practices:AVOID CONTACT W/SKIN & BREATHING VAPORS.DO NOT
EAT,DRINK/SMOKE IN WORK AREA.WASH HANDS PRIOR TO
EATING,DRINKING/SMOKING.
Supplemental Safety and Health
*IF SPILL OCCURS INDOORS,TURN OFF AIR CONDITIONING AND/OR HEATING
SYSTEM TO PREVENT VAPORS FROM CONTAMINATED ENTIRE BUILDING.**DO NOT
REMOVE OR DEFACE LABEL.DO NOT REUSE DRUM WITHOUT RECYCLING OR RECO
NDITIONING IN ACCORDANCE WITH ANY APPLICABLE FEDERAL, STATE OR
LOCAL LAWS.

HCC:T4
Boiling Pt:B.P. Text:165F,74C
Vapor Pres:100 MM HG
Vapor Density:4.6
Spec Gravity:1.30 @ 25/C
Evaporation Rate & Reference:0.4 (ETHER=1)
Solubility in Water:0.07 GM/100 GM @ 25C
Appearance and Odor:CLEAR, COLORLESS LIQUID, MILDLY SWEET ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES, OXIDIZERS, ALUMINUM AND OTHER REACTIVE METALS.
Stability Condition to Avoid:AVOID CONTACT WITH OPEN FLAME, ELECTRIC
ARCS, OR OTHER HOT SURFACES WHICH CAN CAUSE THERMAL DECOMPOSITION.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, CHLORINE.

Waste Disposal Methods:RECOVERED LIQUIDS MAY BE SENT TO A LICENSED
RECLAIMER OR INCINERATION FACILITY. CONTAMINATED MATERIAL MUST BE
DISPOSED OF IN A PERMITTED WASTE MANAGEMENT FACILITY. CONSULT
FEDERAL, STATE OR LOCAL DISP OSAL AUTHORITIES FOR APPROVED
PROCEDURES.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.